synthesis and x-ray structural determination of 2,4,6,8- tetraphenyl- 2,4,6,8- tetraazabicyclo [3.3.0] octane

Authors

s. morteza farnia

ali kakanejadifard

sasan karimi

louis j. todaro

abstract

condensation of glyoxal, formaldehyde and anilines lead to the formation of 2,4,6,8- tetraphenyl and substituted phenyl 2,4,6,8-tetraazabicyclo [3.3.0] octanes. the reactions are sensitive to ph and temperature. ortho derivatives of anilines do not participate in this condensation. x-ray structural determination reveals a cis-dienvelope geometery about the two fused rings.

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Journal title:
iranian journal of chemistry and chemical engineering (ijcce)

Publisher: iranian institute of research and development in chemical industries (irdci)-acecr

ISSN 1021-9986

volume 12

issue 2 1993

Keywords
[ ' p o l y a z a p o l y c y c l i c d e r i v a t i v e ' , 2 , 4 , 6 , 8 , ' t e t r a p h e n y l ' , 2 , 8 , ' t e t r a z y a b i c y c l o [ 3 . 3 . 0 ] o c t a n e ' , ' c i s d i e n v e l o p e g e o m e t e r y ' , ' x ' , ' r a y s t r u c t u r a l a n a l y s i s ' ]

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